Chapter 1 of Warriors Orochi 3 Ultimate
Ma Chao – Start story mode.
Hanbei Takenaka – Start story mode.
Sima Zhao – Start Story mode.
Pang De – Battle of Yiling
Ma Dai – Battle of Yiling
Kunoichi – Battle of Yiling
Zhang Liao – Battle of Ueda Castle
Taishi Ci – Battle of Ueda Castle
Wang Yuanji – Battle of Ueda Castle
Zhuge Dan – Battle of Ueda Castle
Sakon Shima – Battle of Ueda Castle
Kanbei Kuroda – Battle of Dongkou
Xu Huang – Battle of Dongkou
Deng Ai – Battle of Dongkou
Jia Xu – Battle of Dongkou
Ginchiyo Tachibana – Battle of Dongkou
Huang Gai – Battle of Dongkou
Huang Zhong – Complete the Battle of Tetorigawa to unlock Battle of Yiling Redux. Complete that to unlock.
Xu Shu – Complete the Battle of Tetorigawa to unlock Battle of Yiling Redux. Complete that to unlock.
Masanori Fukushima – Battle of Shouchun
Taigong Wang – Battle of Shouchun
Yoshitsune Minamoto – Battle of Shouchun
Ranmaru Mori – Battle of Nagashino
Guo Huai – Battle of Nagashino
Yukimura Sanada – Battle of Nagashino
Zhou Tai – Battle of Nagashino
Hideyoshi Toyotomi – Battle of Nagashino
Yoshihiro Shimazu – Battle of Odawara Castle
Sun Shangxiang – Battle of Odawara Castle
Xiaoquiao – Battle of Odawara Castle
Ding Fen – Battle of Odawara Castle
Kai – Battle of Odawara Castle