Piper
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Piper can be found outside Diamond City. Upon reaching maximum affinity with her, she’ll give you the Gift of Gab perk.
Preston
Preston can be found at the Museum of Freedom in Concord. Upon reaching maximum affinity with him, he’ll give you the United We Stand perk.
Paladin Danse
Paladin Danse can be found at the Cambridge Police Station. Upon reaching maximum affinity with him, he’ll give you the Know Your Enemy perk.
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